钢铁生产的水能关系分析

从钢铁生产过程中水资源使用时的能耗角度研究了钢铁联合企业的水能关系，提出了水能强度的概念来评价企业生产过程中水资源利用的节能水平，建立了钢铁企业的水能关系模型。以中国某大型钢铁联合企业为例，计算并分析了该企业的水能关系。该企业总的水能量为55 709 kW·h/h，重复用水水能量占整个钢铁企业全部水能量的82%，补水水能量占16%，排水水能量占1%；各工序中热轧工序占比最大，其次是炼铁、炼钢工序，冷轧、烧结和炼焦工序较低。该企业的吨钢水能强度为0.208 kW·h/m3，炼铁工序的水能强度最高，热轧、炼钢工序次之，烧结、冷轧和炼焦工序较低。最后，从钢铁生产过程水资源利用的角度得到节能的方向及措施。     

Spillover effects of distribution grid tariffs in the internal electricity market: An argument for harmonization?

In many countries, distribution grid tariffs are being reformed to adapt to the new realities of an electricity system with distributed energy resources. In Europe, legislative proposals have been made to harmonize these reforms across country borders. Many stakeholders have argued that distribution tariffs are a local affair, while the European institutions argued that there can be spillovers to other countries, which could justify a more harmonized approach. In this paper, we quantify these spillovers in a simplified numerical example to give insight and an order of magnitude. We look at different scenarios, and find that the spillovers can be both negative and positive. To be able to quantify these effects, we developed a long-run market equilibrium model that captures the wholesale market effects of distribution grid tariffs. The problem is formulated as a non-cooperative game involving consumers, generating companies and distribution system operators in a stylized electricity market.     

An innovative technology of directional propagation of hydraulic fracture guided by radial holes in fossil hydrogen energy development

Conventional hydraulic fracturing fails to develop low permeability reservoirs of fossil hydrogen energy that are not located in the direction of maximum principal in-situ stress. A new technology of fracture propagation guided by radial holes is proposed, which can realize directional propagation of hydraulic fracture along radial holes in fossil hydrogen energy development. In order to verify this new technology, a model of radial holes combined with hydraulic fracturing is established by the ABAQUS extended finite element method. Simulation results show that radial holes play a guiding role in fractures propagation. The influence extent of seven factors on the directional propagation of hydraulic fracture is listed as follows (from strong to weak): azimuth of radial holes > horizontal in-situ stress difference of fossil hydrogen reservoir > injection rate of fracturing fluid > Young's modulus of rock > permeability of fossil hydrogen reservoir > Poisson ratio of rock > viscosity of fracturing fluid. True tri-axial experiment is carried out to verify the accuracy of numerical simulation, and the result is consistent with numerical model, which indicates that numerical simulation is reliable.     

Determination of Acoustical Parameters of Aqueous Solution of Kolliphors Binary Mixtures Using Density,Speed of Sound,Viscosity, and Surface Tension Measurements

Measurements of density, speed of sound, and surface tension as well as viscosity of aqueous Kolliphor® ELP (ELP) and Kolliphor® RH 40 (RH40) solutions as well as binary mixtures at different surfactant mole fractions were made at 293 K to investigate their aggregation behavior. The free volume, internal pressure, and molar cohesive energy were calculated and compared to the specific acoustic impedance and intermolecular free length to obtain qualitative information about the character of interactions between the surfactant molecules in the mixture through the water phase.     

Excellent Energy Storage and Charge-discharge Performances in PbHfO3 Antiferroelectric Ceramics

Single phase PbHfO₃ antiferroelectric ceramics were prepared via rolling process. It is revealed that the rolling process can reduce the grain size and increase the bulk density, which lead to the enhanced breakdown strength up to 268 kV/cm versus 219 kV/cm of samples using the conventional solid-state method. As a result, high recoverable energy density of 7.6 J/cm³ with an efficiency of 80.8 % was achieved. Meanwhile, a large current density of 1381 A/cm² and an ultrahigh peak power density up to 170 MW/cm³ were observed under 250 kV/cm. In addition, unique electrical polarization response characteristics at different electric fields and temperature-induced structural phase transitions were also investigated. The energy storage performance and charge-discharge properties of PbHfO₃ were first studied in this communication and all the results indicate that PbHfO₃ ceramic is a promising candidate for pulse power applications.     

Application of adhesively bonded single lap joints for fracture assessment of adhesive materials

In this study, a method has been proposed to obtain the failure envelope of brittle adhesives using the experimental failure loads of precracked single lap joints (SLJs). The proposed technique is based on the principles of linear elastic fracture mechanics (LEFM), on J-integral relations, and on results of a numerical analysis. Compared to the previous approaches, the introduced experimental method has some advantages such as low manufacturing costs and simpler test procedure. The proposed method can also provide a wide range of mode mix ratios without the need of an additional apparatus. The fracture envelope obtained from the proposed method was then verified by performing some fracture tests including double cantilever beam (DCB), end-notched flexure (ENF), and single leg bending (SLB) specimens. Good correlation was seen between the fracture envelopes of the proposed method and the ones obtained from the fracture mechanics experiments.     

Curing kinetics and mechanical properties of fast curing epoxy resins with isophorone diamine and N-(3-aminopropyl)-imidazole

Fast curing epoxy resins were prepared by the reactions of diglycidyl ether of bisphenol A with isophorone diamine (IPD) and N-(3-aminopropyl)-imidazole (API), and their curing kinetics and mechanical properties influenced by IPD content were also investigated. The analysis of curing kinetics was based on the nonisothermal differential scanning calorimetry (DSC) data with the typical Kissinger, Ozawa, and Flynn–Wall–Ozawa models, respectively. The glass-transition temperature was also measured by the same technique. Additionally, the mechanical properties including flexural, impact, and tensile performances were tested, and the curing time was estimated by isothermal DSC. The degree of cure (α) dependency of activation energy (E_a ) revealed the complexity of curing reaction. Detailed analysis of the curing kinetics at the molecular level indicated that the dependence of E_a on the α was a combined effect of addition reaction, autocatalytic reaction, viscosity, and steric hindrance. From the nonisothermal curves, the curing reaction mechanism could be proposed according to the increasingly obvious low temperature peaks generated by the addition reaction of epoxy group with the primary amines in API and IPD molecules. Using the preferred resin formulation, the resin system could be cured within 10 min at 120 °C with a relatively good mechanical performance. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47950.     

Frequency dependence of plasma characteristics at different pressures in cylindrical inductively coupled plasma source

The effects of driving frequency on plasma parameters and electron heating efficiency are studied in cylindrical inductively coupled plasma (ICP) source. Measurements are made in an Ar discharge for driving frequency at 13.56/2 MHz, and pressures of 0.4–1.2 Pa. In 13.56 MHz discharge, higher electron density (n_e) and higher electron temperature (T_e) are observed in comparison with 2 MHz discharge at 0.6–1.2 Pa. However, slightly highern_e andT_e are observed in 2 MHz discharge at 0.4 Pa. This observation is explained by enhanced electron heating efficiency due to the resonance between the oscillation of 2 MHz electromagnetic field and electron-neutral collision process at 0.4 Pa. It is also found that the variation ofT_e distribution is different in 13.56 and 2 MHz discharge. For ICP at 13.56 MHz, T_e shows an edge-high profile at 0.4–1.2 Pa. For 2 MHz discharge,T_e remains an edge-high distribution at 0.4–0.8 Pa. However, the distribution pattern involves into a center-high profile at 0.9–1.2 Pa. The spatial profiles ofn_e remain a center-high shape in both 13.56 and 2 MHz discharges, which indicates the nonlocal kinetics at low pressures. Better uniformity could be achieved by using 2 MHz discharge. The effects of gas pressure on plasma parameters are also examined. An increase in gas pressure necessitates the rise ofn_e in both 13.56 and 2 MHz discharges. Meanwhile, T_e drops when gas pressure increases and shows a flatter distribution at higher pressure.     

最优化算法与纯元素谱剥离相结合的能量色散X射线荧光谱解谱方法

在进行能量色散X射线荧光光谱(EDXRF)解谱时,如果给定样品的元素构成,采用纯元素谱图剥离的方式会更加合理,但由于每个元素的谱线都不止一条,如果仅仅针对主线对齐做剥离,会导致结果的严重失真,同时剥离次序对解谱结果有较大影响。介绍了一种最优化算法与纯元素谱剥离相结合的EDXRF解谱方法,该方法以多个纯元素谱的强度大小和峰位漂移道数作为变量构建残差方程,并用最优化计算的方法去调整,直至残差达到极小。实验采用强度顺序剥离、能量顺序剥离和最优化算法拟合3种方法分别对谱线重叠较为严重的La-Ce-Pr-Nd混合液样品的L系谱线进行了解析,结果表明最优化计算方法拟合的谱图与原始谱的残差 (1415.0)比另两种方法(166094.0和3192.7)大幅度缩小,拟合谱与原始谱更为吻合,并且方法在实现时对初值不敏感,解谱精度也不依赖于剥离次序。     

区分站点状态的两级轮询控制系统

针对提高轮询控制模型工作效率和区分网络优先级的问题，提出了区分站点忙闲状态的完全-门限两级轮询控制模型（ETTPSS）。模型以两级优先级为基础，依据站点的忙闲状态采用并行处理方式只对忙站点进行信息分组发送服务。模型既能区分传输服务优先级又能避开对无信息分组的空闲站点的查询，从而提高了模型资源利用率和工作效率。运用概率母函数与马尔可夫链相结合的方法对该模型进行理论分析研究，精确解析了模型各个重要性能参数。仿真实验结果表明，仿真值与理论值近似相等，说明理论分析正确合理。与普通轮询模型相比，该模型性能大幅度提高。